ChemInform Abstract: Molecular Addition Compounds. Part 15. Synthesis, Hydroboration, and Reduction Studies of New, Highly Reactive tert-Butyldialkylamine-Borane Adducts

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  2000 organo-boron compounds, acyclic O,N,S derivatives organo-boron compounds, acyclic O,N,S derivativesS 0041 01 - 192 Molecular Addition Compounds. Part 15. Synthesis, Hydrob-oration, and Reduction Studies of New, Highly Reactive tert-Butyldialkylamine–Borane Adducts.  — Complexation of tert-butyldialkylamines (I) with BH 3  yields stable, highly reactive liquid adducts,especially from (Ic), (Id), and (Ig), as borane carriers for hydroborationreactions, which can serve as eco-friendly substitutes for the currently popularhydroborating-reducing agents Me 2 S · BH 3  and THF · BH 3 . — (BROWN, HER-BERT C.; KANTH, JOSYULA V. B.; DALVI, PRAMOD V.; ZAIDLEWICZ,MAREK; J. Org. Chem. 64 (1999) 17, 6263-6274; Brown and Wetherill Lab.Chem., Purdue Univ., West Lafayette, IN 47907, USA; EN)1
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